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David’s Story: La Historia De David

為了解決Honda N ONE的問題，作者Velez, Edia L. 這樣論述：

This is the story of the fascinating King David. It begins when he is born and a curious scene occurs around his crib. As their seven brothers were older they went with their father Jesse to the countryside to take care of the sheep, to work in agriculture, to fish and sell sheep and their wool, etc

. David stayed at home with his mother, Nitzevet, and she taught him the Hebrew letters and also taught him how to do household chores. David was very intelligent and learned to prepare olive oil, he learned how to prepare wine from the sweet grapes of his vineyard, he learned to prepare the delicio

us bread they ate every day and the rich cheese from the milk of the sheep. The rabbi taught David about the stars and to read Hebrew. One day David found a turtle shell and his father helped him make a lyre with her. He learned to play her. With much love he played the lyre, danced and sang to his

Lord God. He worshiped his God Adonai by playing his lyre, singing and dancing. He was very strong and brave. He defeated a lion and a wild bear to defend his sheep. With a pebble and a sling he defeated the fearful giant Goliath of the Philistines. He won the war for Israel and became the king of I

srael. He was a great king. As a poet, musician, shepherd of sheep, warrior and king, he always loved and served his God Adonai. Esta es la historia del fascinante Rey David. Empieza cuando l nace y ocurre una escena curiosa alrededor de su cuna. Como ya sus siete hermanos eran mayores se iban con

su padre Jesse al campo a cuidar de las ovejas, a trabajar en la agricultura, a pescar y a vender ovejas y su lana, etc. David se quedaba en su casa con su madre, Nitzevet y ella le ense aba las letras hebreas y le ense aba tambi n a hacer las tareas del hogar. David era muy inteligente y aprendi a

preparar el aceite de oliva, aprendi a preparar vino de las dulces uvas de su vi edo, aprendi a preparar el delicioso pan que com an todos los d as y el rico queso de la leche de las ovejas. El rabino le ense a David acerca de las estrellas y a leer Hebreo. Un d a David encontr un caparaz n de

tortuga y su padre le ayud a hacer una lira con ella. l aprendi a tocarla. Con mucho amor tocaba la lira, danzaba y cantaba a su Se or Dios. l adoraba a su Dios Adonai tocando su lira, cantando y danzando. l era muy fuerte y valiente. Venci a un le n y a un oso salvaje para defender a sus ove

jas. Con una piedrita y una honda venci al temeroso gigante Goliat de los filistinos. l gan la guerra para Israel y se convirti en el rey de Israel. Fue un gran rey. Como poeta, m sico, pastor de ovejas, guerrero y rey, siempre am y sirvi a su Dios Adonai. Edia L. Velez was born in San Sebas

tian, Puerto Rico. She moved to the United States during 1960, graduated from Houston Baptist University, and taught elementary bilingual education at Houston Independent School District (HISD). She graduated from the Institute of Children’s Literature in Connecticut. In 2001 she retired from the US

Department of Education in Washington, DC, where she worked for eleven years. She has published four bilingual books for children: Jessica’s Summer Vacation (Las vacaciones de verano de Jéssica), The Tale of Bad Guts and Bad Blood (El cuento de Mala Entrañita y de Mala Sangre), and Zoe Meets Pierre

(Zoé conoce a Pierre). Edia has two daughters, Edia Zoe Lugo Husband and Lynette Lugo Petrie; a son, David Lugo, married to Mónica; and five grandchildren. Her hobbies are writing for children, gardening, and reading. She lives in Buda, Texas. Edia L. Velez nació en San Sebastian, Puerto Rico. Ella

se mudó a los Estados Unidos durante los 1960. Se graduó de Houston Baptist University. Enseñó escuela elemental bilingue en Houston Independent School District (HISD). Se graduó del ＂Institute of Children’s Literature＂ en Connecticut. En 2001, se retiró del Departamento de Educación de los Estados

Unidos de America en Washington, DC, en donde trabajó por once años. Ella ha publicado cuatro libros bilingues para niños: Jessica’s Summer Vacation, (Las vacaciones de verano de Jéssica), segundo, The Tale of Bad Guts and Bad Blood (El cuento de Mala Entrañita y de Mala Sangre), tercero, Lynette’s

Untouchable Bubble (Lynette y su Burbuja Intocable), y cuarto, Zoe Meets Pierre (Zoé Conoce a Pierre). Ella tiene dos hijas, Edia Zoé Lugo Husband y Lynette Lugo Petrie, y su hijo David Lugo, casado con Mónica, y cinco nietos. Su entretenimiento favorito es escribir para niños, trabajar en su jardí

n, y leer. Ella vive en Buda, Texas.

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布里斯洛中間體自由基反應機制之理論研究

為了解決Honda N ONE的問題，作者謝明修 這樣論述：

含氮雜環卡賓（N-heterocyclic carbene）催化之化學反應中，布里斯洛中間體（Breslow intermediate）扮演重要的催化角色。布里斯洛中間體能以親核基（nucleophile）或自由基（radical）之形式參與反應。本論文探討布里斯洛中間體之自由基特性及形成機制（mechanism），其自由基可從氫自由基轉移或直接氧化形成。安息香縮合反應（benzoin condensation）中，布里斯洛中間體將氫原子轉移至苯甲醛（benzaldehyde）以形成自由基，此自由基可結合形成安息香產物，或排除反應之副產物，使其重新進入催化反應。唯此路徑之反應能障高於傳統非自

由基路徑。此研究亦探討四種布里斯洛中間體之不同電子組態的位能面。其中烯醇鹽（enolate）形式能產生偶極束縛態（dipole-bound state），此為產生自由基之新路徑；拉電子基（electron-withdrawing group）以及立體障礙基（bulky groups）可穩定基態。另外，我們亦研究布里斯洛中間體之碎片化（fragmentation）與重組（rearrangement）。布里斯洛中間體之催化反應可能因其碳氮鍵斷裂而中止，形成碎片。我們證實其反應中可以形成自由基，亦可形成離子。反應趨向之路徑與布里斯洛中間體之羥基的質子化型態有關。碎片化反應亦可視為轉酮醇酶（tran

sketolase）中之噻胺（thiamin）催化反應中之副反應；此研究證實轉酮醇酶透過限制布里斯洛中間體之結構與質子化型態，使其碳氮鍵斷裂需更高之反應能量，進而抑制此副反應。